Tuesday, May 31, 2011

Polymers

Definition
Polymers are long chains of molecules made from combination of many small molecules called monomers. Polymerisation is a process of combining monomers to form a long chain of molecules.

source: http://hsc.csu.edu.au/senior_science/options/polymers/2973/SS951.html
Naturally Occurring Polymers

Are polymers that occur naturally, like...:

  1. Rubber
  2. Cellulose
  3. Starch
  4. Protein
  5. Fat
  6. Nucleic acid
Synthetic Polymer

Synthetic polymers are often referred to as "plastics", such as the well-known polyethylene and nylon.



Uses of some General Synthetic Polymers with their Names and Monomer Units are as Follows:-

Name(s)FormulaMonomerUses
Polyethylene
low density (LDPE)
–(CH2-CH2)nethylene
CH2=CH2
Used in film wrap, plastic bags
Polyethylene
high density (HDPE)
–(CH2-CH2)nethylene
CH2=CH2
Used in electrical insulation
bottles, toys
Poly(vinyl chloride)
(PVC)
–(CH2-CHCl)nvinyl chloride
CH2=CHCl
Used in pipes, siding, flooring.etc.
Poly(vinylidene chloride)
(Saran A)
–(CH2-CCl2)nvinylidene chloride
CH2=CCl2
Used in seat covers, films etc.
Polystyrene
(PS)
–[CH2-CH(C6H5)]nstyrene
CH2=CHC6H5
Used in toys, cabinets
packaging etc.
Polyacrylonitrile
(PAN, Orlon, Acrilan)
–(CH2-CHCN)nacrylonitrile
CH2=CHCN
Used in rugs, blankets
clothing etc.
Polytetrafluoroethylene
(PTFE, Teflon)
–(CF2-CF2)ntetrafluoroethylene
CF2=CF2
Used in non-stick surfaces, electrical insulation
Poly(vinyl acetate)
(PVAc)
–(CH2-CHOCOCH3)nvinyl acetate
CH2=CHOCOCH3
Used in latex paints, adhesives etc.
cis-Polyisoprene
natural rubber
–[CH2-CH=C(CH3)-CH2]nisoprene
CH2=CH-C(CH3)=CH2
Requires vulcanization
for practical use and vulcanized rubber is used in tyres etc.
Polychloroprene (cis + trans)
(Neoprene)
–[CH2-CH=CCl-CH2]nchloroprene
CH2=CH-CCl=CH2
It is a synthetic rubber and is
oil resistant so used in mats etc.

source: http://www.tutorvista.com/chemistry/synthetic-polymers-and-their-uses

Properties of Synthetic Polymers

Synthetic polymers are not biodegradable (not decomposed by microorganism). The careless disposal of items made from synthetic polymers such as plastic causes environmental pollution. The effects of burning and careless disposal of items made from synthetic polymers on the environments are as follow;
    (a) Burning of synthetic polymers
        ∆ Releases pollutants that endanger health such as smoke, gasses that are smelly, poisonous and corrosive such                          a          as sulphur dioxide, pollutants that cause acid rain and the green house effect.

    (b) Careless disposal of synthetic polymers
        ∆ Spoils the beauty of the environment.
        ∆ Causes flash floods during heavy rainfall.
        ∆ Endangers marine lifelike turtles that accidentally eat polymers such as plastics as food

The best way to manage used items made from synthetic polymers is to recycle them. Plastics that are biodegradable can be used instead to reduce environmental pollution.


References


-Longman Essential Chemistry Spm

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